Mercury(II) bromideIUPAC traditional InChIKey:NGYIMTKLQULBOO-UHFFFAOYSA-L Copy CAS registry Number: 7789-47-1Other names:HgBr2;Mercury(2)bromide;Mercuric bromide;Mercury bromide;Mercury bromide (HgBr2);Mercury(ii) bromide (1:2);UN 1634;Mercury dibromideInformation ~ above this page:Other data available:Data at various other public piersonforcongress.com sites:Options:

Reaction thermochemistry data

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Data compiled as suggested in comments:MS - José A. Martinho SimõesALS - Hussein Y. Afeefy, Joel F. Liebman, and also Stephen E. Stein

Note: Please consider using thereaction find for this species. This page allows searchingof every reactions involving this species. A basic reaction searchform is additionally available. Future version of this site may rely onreaction search pages in place of the enumerated reactiondisplays watched below.

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Individual Reactions

*
(l)+2
*
(l) = 2
*
(g)+
*
(cr)

By formula: C2H6Hg(l)+2Br2(l) = 2CH3Br(g)+Br2Hg(cr)

QuantityValueUnitsMethodReferenceComment
ΔrH°-302.1 ± 2.5kJ/molRSCHartley, Pritchard, et al., 1950Please also see Pedley and also Rylance, 1977 and also Cox and also Pilcher, 1970.; MS

C6H14Hg(l)+

*
(cr) = 2C3H7BrHg(cr)

By formula: C6H14Hg(l)+Br2Hg(cr) = 2C3H7BrHg(cr)

QuantityValueUnitsMethodReferenceComment
ΔrH°-88.8 ± 1.5kJ/molRSCMortimer, Pritchard, et al., 1952Please likewise see Pedley and Rylance, 1977 and also Cox and Pilcher, 1970.; MS

*
(l)+
*
(cr) = 2
*
(cr)

By formula: C2H6Hg(l)+Br2Hg(cr) = 2CH3BrHg(cr)

QuantityValueUnitsMethodReferenceComment
ΔrH°-61.0 ± 3.1kJ/molRSCHartley, Pritchard, et al., 1950Please additionally see Pedley and also Rylance, 1977 and Cox and also Pilcher, 1970.; MS

C6H14Hg(l)+

*
(cr) = 2C3H7BrHg(cr)

By formula: C6H14Hg(l)+Br2Hg(cr) = 2C3H7BrHg(cr)

QuantityValueUnitsMethodReferenceComment
ΔrH°-75.9 ± 1.3kJ/molRSCMortimer, Pritchard, et al., 1952Please additionally see Pedley and also Rylance, 1977 and Cox and also Pilcher, 1970.; MS

*
(l)+
*
(cr) = 2C6H5BrHg(cr)

By formula: C12H10Hg(l)+Br2Hg(cr) = 2C6H5BrHg(cr)

QuantityValueUnitsMethodReferenceComment
ΔrH°-35.5 ± 1.2kJ/molRSCHartley, Pritchard, et al., 1951Please likewise see Pedley and also Rylance, 1977 and Cox and Pilcher, 1970.; MS

*
(l)+
*
(cr) = 2C2H5BrHg(cr)

By formula: C4H10Hg(l)+Br2Hg(cr) = 2C2H5BrHg(cr)

QuantityValueUnitsMethodReferenceComment
ΔrH°-74.5 ± 4.6kJ/molRSCHartley, Pritchard, et al., 1951Please additionally see Pedley and Rylance, 1977 and also Cox and Pilcher, 1970.; MS

2

*
+
*
=
*
+2
*

By formula: 2C6H5Br+Br2Hg = C12H10Hg+2Br2

QuantityValueUnitsMethodReferenceComment
ΔrH°328.6 ± 3.3kJ/molCmChernick, Skinner, et al., 1956liquid phase; ALS

References

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Hartley, Pritchard, et al., 1950Hartley, K.; Pritchard, H.O.; Skinner, H.A.,Thermochemistry of metallic alkyls. III.?mercury dimethyl and mercury methyl halides,Trans. Faraday Soc., 1950, 46, 1019, https://doi.org/10.1039/tf9504601019.

Pedley and Rylance, 1977Pedley, J.B.; Rylance, J.,Computer Analysed Thermochemical Data: Organic and also Organometallic Compounds, college of Sussex, Brigton, 1977.

Cox and Pilcher, 1970Cox, J.D.; Pilcher, G.,Thermochemistry of Organic and also Organometallic Compoundsin Academic Press, brand-new York, 1970.

Mortimer, Pritchard, et al., 1952Mortimer, C.T.; Pritchard, H.O.; Skinner, H.A.,Thermochemistry the metallic alkyls. Part V.?Mercury di-propyl and also mercury di-isopropyl,Trans. Faraday Soc., 1952, 48, 220, https://doi.org/10.1039/tf9524800220.

Hartley, Pritchard, et al., 1951Hartley, K.; Pritchard, H.O.; Skinner, H.A.,Thermochemistry that metallic alkyls. IV. Mercury diethyl and mercury diphenyl,Trans. Faraday Soc., 1951, 47, 254, https://doi.org/10.1039/tf9514700254.

Chernick, Skinner, et al., 1956Chernick, C.L.; Skinner, H.A.; Wadso, I.,Thermochemistry of metallic alkyls. Part 7.-The warmth of development of mercury diphenyl, and also of mercury phenyl chloride,Trans. Faraday Soc., 1956, 52, 1088-1093.

Notes

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Symbols provided in this document:
ΔrH°Enthalpy that reaction at conventional conditions
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