Other alkali steel salts or LiX salt with various other anions often develop no improvement.

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From: Encyclopedia the Electrochemical power Sources, 2009

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M. Tamm, R.J. Baker, in an extensive Organometallic Chemistry III, 2007 team 1 and also 2 metal complexes

Alkali metal salts of − are popular compounds and also are one of the key precursors in organomolybdenum chemistry. Whilst the synthetic methods are well documented, couple of further studies have actually been carried out. There is only one example of a new Mo–group 2 complicated reported since 1994. The reaction the the beryllium facility ArBeCl (Ar = terphenyl ligand) with Na offers rise to a unique example of a beryllium isocarbonyl structure, ,912 in contrast to reactivity through ArGeCl which forms multiply bonded Mo–Ge complexes. The beryllium compound has been structurally characterized and also shows structural and spectroscopic features regular with isocarbonyl linkages.913

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Synthesis: Carbon through Two fastened Heteroatoms v at least One Carbon-to-Heteroatom multiple Link

Peter Quayle, in substantial Organic Functional team Transformations, 1995 The Semmelhack reaction

The alkali metal salts (7) and also (8) are easily prepared by reduction of the amino complicated (9) through lithium or sodium naphthalenide in THF under strictly anaerobic conditions. A stock solution of the salt (7) or (8) in THF is climate reacted v a carboxylic mountain chloride in THF at −78 °C to afford the acylate complex (10) which might be capped in the common manner in stimulate to create the carbene complex. The salt (7) and (8) space unreactive towards a range of functional groups (e.g., esters, benzylic halides, etc.) thereby allowing the arrival of the carbene moiety in a chemoselective fashion (Scheme 2) 87OM1839>. All at once yields are similar to those reported by Fischer in the instances where straight comparisons can be made.

Scheme 2.

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Dichalcogenoimidodiphosph(in)ate Ligands☆

I. Haiduc, in reference Module in Chemistry, molecule Sciences and also Chemical Engineering, 2013

Group 1 Metals: Li, Na, K, Rb, Cs

The alkali metal salts are important starting materials for practicaly any kind of dichalcogenoimidodiphosphinato complex, in metathesis reaction with metal salts and also are usually acquired by deprotonation that bis(chalcogenophosphino)amines (Q)R2PNHPR2(Q) (Q = O, S, Se, Te) through various simple reagents.

Lithium dichalcogenoimidodiphosphinates (TMEDA)Li v Q = Se and also Te, and also mixed ligand derivaties (TMEDA)Li through Q = S and Se were all set from (Se)Pri2PN = PPri2H by deprotonation v BuLi in TMEDA (tetramethylethylenediamine), followed by addition of tellurium. Similarly, the thio link was obtained from (Te)Pri2PN = PPri2H after enhancement of sulfur to the deprotonated derivative. The heavy state structure of the link was established by X-ray diffraction. In enhancement a polymeric framework was established in the hard state for Na whereby Q = Se and also Te.11

Sodium crown ether complexes v crown = 15-crown-5 and benzo-15-crown-5, to be prepared and also structurally defined by X-ray diffraction.12

Nine lithium, rubidium and cesium crown ether complexes v - anions together ligands (Q = O, S, Se) were prepared and also the crystal structures were established for (where Q = S, Se), and also (where Q = O, S, Se).13

The reaction that Pri2PNHPPri2 through elemental selenium affords great yields that (Se)Pri2PNHPPri2(Se) which can be deprotonated with NaOMe to provide the salt salt, Na; the reagent was offered for the synthesis of brand-new Cu, Ag and also Au complexes, helpful as single source precursors for I/III/Vi photovoltaic materials, e.g. CuInSe2.14

Lithium salts of unsymmetrical dichalcogenoimidodiphosphinato anions - (Q = S, Se) are oxidized by element iodine come afford the cyclic cations + include five-membered rings. The oxidation v cobaltocene regenerates the anions together cobaltocenium salts Cp2Co (Q = S, Se).15

The ditelluroimidodiphosphinato salt Na(TMEDA) was an initial obtained by treating Na v elemental tellurium in the visibility of TMEDA.16

Sodium salt of diseleno- and ditelluroimidodiphosphinates, Na (where Q = Se, Te) have actually been prepared and also structurally characterized.17 The ditelluroimidodiphosphinato anion - is a centrosymmetric dimer in the heavy state v weak Te…Te second bonding interactions.18

New mixed, unsymmetrical dichalcogenoimidodiphosph(in)ates, with R, R’ = Ph, OPh, Pri; Q, Q’ = O, S, Se, have been ready by condensation that R2P(Q)NH2 (R = Ph, OPh; Q = O, S, Se) through R’2P(Q’)Cl (R’ = Pri, Ph, OPh; Q’ = O, S, Se). Deprotonation through KOBut afforded the potassium salts, which deserve to react through PdCl2 to form the matching palladium(II) complexes.19

Sodium tert-butyldichalcogenoimidodiphosphinates, Na(TMEDA)<(QBut2PNPBut2Q)>, through Q = S, Se, Te, have actually been prepared and their one-electron oxidation v iodine produced neutral dimers 2. The sulfur and also selenium derivatives exhibition acyclic frameworks with elongated chalcogen-chalcogen bonds, vice versa, the tellurium derivative is a spirocyclic compound. The two-electron oxidation the Na(TMEDA), where Q = Se, Te, through iodine produced cyclic cations + isolated together iodide salts.20

The alkali steel salts of dialkyl H-phosphonates react through N-alkoxypyridinium salt to give, via addition–elimination, dialkyl 2-pyridinylphosphonates (e.g. 190) in acceptable yield (Fig. (301,302). They likewise react through 1-triphenylmethylpyridinium salt that lack α-substituents come generate similarly dialkyl 4-pyridinylphosphonates (191192) (303,304). The synthetic of dialkyl heteroarylphosphonates, consisting of dialkyl pyridinylphosphonates, by palladium-catalysed coupling of dialkyl H-phosphonates with heteroaryl bromides or chlorides is questioned in a previous ar (Table (285). A an approach for the preparation of diethyl 3-pyridinylphosphonate (193) based on such chemistry is provided in this section (292). The ready of dinucleoside 2- and 4-pyridinylphosphonates has also been reported (305,306). Pyridinylphosphonic mountain are also of biological interest (307).

Diethyl 2-pyridinylphosphonate (EtO)2P(O)C5H4N-2 (190) (301). n-Butyllithium (23% in hexane, 63 ml, 0.15 mol) was included dropwise end 2 h to stirred diethyl H-phosphonate (25.0 g, 0.18 mol) cooled to −20 to −30 °C. Come the result diethyl lithium phosphite was included N-methoxypyridinium methyl sulfate N-oxide (14.3 g, 0.15 mol) and dimethyl sulfate (18.9 g, 0.15 mol)> in diethyl H-phosphonate (40 ml) end 1 h in ~ −15 °C. ~ addition, the mixture to be stirred in ~ room temperature for 12 h and also water (100 ml) was added. The mixture to be extracted through chloroform (3 × 75 ml) and also the necessary extract to be separated into neutral and an easy fractions by extraction (4 M hydrochloric acid), basification and re-extraction with chloroform. The basic section was distilled to provide diethyl 2-pyridinylphosphonate (22.9 g, 67%). Bp 105–112 °C/0.08 mmHg. Redistillation gave an analytically pure sample (bp 96–97 °C/0.03 mmHg).

Diisopropyl 4-pyridinylphosphonate (i-PrO)2P(O)C5H4N-4 (192) (303). Pyridine (10 ml) was included to a stirred equipment of triphenylcarbenium tetrafluoroborate (19.0 g, 58 mmol) in dichloromethane (250 ml) with cooling. ~ standing at 5 °C overnight, the result crystals that triphenylmethylpyridinium tetrafluoroborate were collected by filtration (13.6 g). To a suspension of this crystals in benzene (130 ml) was included a solution of diisopropyl sodium phosphite (35 mmol) in diisopropyl H-phosphonate (14 ml) over 45 min at 5–10 °C. The mixture to be heated under reflux for 2 h and enabled to cool. Water (50 ml) was added and the organic phase was separated and extracted through 3 M hydrochloric mountain to recover the basic portion. Distillation the the crude oil base yielded pyridine and diisopropyl 4-pyridinylphosphonate (2.5 g, 30%; bp 104–105 °C/0.4 mmHg) which solidified on standing. Recrystallisation from hexane gave the pure product. Mp 45–46 °C.

Diethyl 3-pyridinylphosphonate (i-PrO)2P(O)C5H4N-3 (193) (292). Pd(PPh3)4 (72 mg, 0.06 mmol, 5 mol%), Cs2CO3 (489 mg, 1.50 mmol) and 3-bromopyridine (0.21 g, 1.38 mmol) were placed in a microwave tube. The pipe was sealed v a lid and also filled v nitrogen gas, by using three cycles the vacuum, and then nitrogen. THF (5 ml) and also diethyl H-phosphonate (0.17 g, 1.25 mmol) were added successively with the septum. The pipe was cook in the microwave oven (SmithCreator single-mode microwave cavity – an individual Chemistry AB, Uppsala, Sweden – producing a consistent irradiation the 300 W at 2450 MHz) for 10 min at 120 °C. ~ cooling, the solids to be filtered off and also washed through dichloromethane. The merged filtrate and washings were evaporated. The residue was purified by column chromatography top top silica gel, eluting with 95:5 dichloromethane–methanol, to offer the title link (0.26 g, 86%). δP (162 MHz, CDCl3) 15.7 ppm.

L.N. Sidorov, S.I. Lopatin, in Encyclopedia of Spectroscopy and also Spectrometry (Third Edition), 2017

Electron Affinity Determination

Addition of facility alkali metal salts to a high-temperature system leads to an unfavorable ion development in the vapor. KEMS-IME have the right to be applied to electron affinities and also the estimation of an adverse ion enthalpies the formation. The EA that fluorides and oxides of change metals in their greater oxidation says were determined. Almost all of these compounds have EA in the range 3.5–7.0 eV. Applications of this an approach to fullerene vapors has yielded the electron affinities for the series of higher fullerenes Cn (n ¼ 70, 72,…, 106).

Preparation that the alkali metal salts the purine bases (commonly v sodium hydride) permits the generation of a solid nitrogen nucleophile on the purine base (Scheme 4). This varieties can be used for direct SN2 displacement the an appropriate leaving group from the C-1 position of the carbohydrate. When used in conjunction with the α-chloro derivative of 2-deoxyribose (11), the reaction proceeds with inversion of construction to create only the β-anomer that the 2′-deoxynucleoside (21). In some cases regioisomeric products an outcome (see (24) and (25) in scheme 4), however such product mixture can often be much more easily separated 보다 the corresponding mixtures that α- and β-anomeric isomers. Owing to the stereochemical specificity of this reaction, it is more than likely the most effective glycosylation procedure because that the ready of 2′-deoxynucleoside derivatives that the purine heterocycles.

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The reaction of an alkali metal salt of a hydrocarbon, alcohol, or amine gives a convenient means to prepare a variety of both coordination and organometallic complexes (eqn <8>). That is, perhaps, the most broadly applicable that the general methods, usable through the team 2 steels from beryllium to barium. The most common pairing the reagents has been v potassium salts and alkaline-earth dihalides, specifically the iodides, since removal that the by-product (insoluble alkali steel salts) is the many straightforward v this combination. The usage of BeBr2(SMe2)2 offers a soluble kind of beryllium bromide once ethers need to be avoided since it is dissolve in Me2S and CH2Cl2.68 symptom can happen with lithium-based reagents, which seem particularly prone come the formation of anionic “-ate” complexes (e.g., eqn <9>).69,70 such reactions additionally can take place with potassium salt (e.g., eqn <10>) and also can be insidious since the existence of the potassium may not be basic to detect.71 for example, some varieties of calciate complexes, e.g., KxCayx+ 2y, can form with substoichiometric amounts of K, and calciates the the form (L)nK2Ca4 (L = neutral coligands) kind during the metathesis reaction of K with CaI2 if any kind of excess the the potassium amide is present, also if no in exact stoichiometric ratio.72 Halide metathesis can also be used to derivatize existing group 2 compounds, together in eqn <11>.73


Acylation the amine salts or alkali metal salts of hydrogen selenide using acid chlorides can be supposed to be a general route come bis(acyl) selenides. However, the initial commodities in this reaction are not the desired bis(acyl) selenides but O-acyl selenonesters as shown in Schemes 21 and 22 91JOC3776>. In the case of aliphatic acid chlorides, the resulting O-acyl selenonesters quickly isomerize to much more stable bis(acyl) selenides 72ACS1465, 89ZN(B)1050>. However, aromatic selenonesters are more stable 보다 aliphatic ones, fan to conjugation between the aromatic ring and the seleno-carbonyl group, and also therefore carry out not isomerize come bis(acyl) selenides 72ACS1465>.